Advances in bifunctional catalysis for higher alcohol synthesis from syngas
نویسندگان
چکیده
منابع مشابه
Bifunctional catalysis
Bifunctional catalysis concerns the use of low molecular weight, structurally defined molecules possessing two distinct functional groups to bring about new reactivity and/or selectivity in a reaction of interest. The reactions are typically polar addition reactions of pronucleophiles and electrophiles where, ideally, simple low-cost starting materials are converted into high-value, stereochemi...
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Enzymes are the most efficient catalysts known working in an aqueous environment near 12 room temperature. The folding of individual polymer chains to functional single-chain nanoparticles 13 (SCNPs) offers many opportunities for the development of artificial enzyme-mimic catalysts 14 showing both high catalytic activity and specificity. In this review, we highlight recent results 15 obtained i...
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The influence of Mo particle size on the catalytic activity and product selectivity of alkalized MoS2 nanocatalysts has been investigated. Nanocatalysts are prepared using a microemulsion technique with water-to-surfactant ratios of 1-12. Three different techniques, including XRD, TEM, and hydrogen chemisorption were used to determine the molybdenum average particle size and their activity and ...
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15 صفحه اولBifunctional phase-transfer catalysis in the asymmetric synthesis of biologically active isoindolinones
New bifunctional chiral ammonium salts were investigated in an asymmetric cascade synthesis of a key building block for a variety of biologically relevant isoindolinones. With this chiral compound in hand, the development of further transformations allowed for the synthesis of diverse derivatives of high pharmaceutical value, such as the Belliotti (S)-PD172938 and arylated analogues with hypnot...
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ژورنال
عنوان ژورنال: Chinese Journal of Catalysis
سال: 2013
ISSN: 1872-2067
DOI: 10.1016/s1872-2067(11)60496-8